International Journal Publication

Enhancing efficiency and stability of perovskite solar cells through two-step deposition method with the addition of cesium halides to PbI2 precursor

Author affiliations and roles
  1. aChang Gung University
  2. bMing Chi University of Technology
  3. cCentral Electrochemical Research Institute
  4. dHong Kong Polytechnic University
  5. eChang Gung Memorial Hospital
  6. fChang Gung University of Science and Technology
  • *Corresponding authors: Huang, Yu-Ching, Wu, Ming-Chung, Lee, Kun-Mu.

Organic Electronics, 120, 106847 (2023).

Research topic: Perovskite Solar Cells

Abstract

Perovskite films with few defects play a key role in preparing high-performance perovskite solar cells (PSCs). Here, cesium halides, such as CsCl, CsBr, and CsI, were introduced as a modulator into 1st PbI2 precursor for manipulating the crystallization of perovskite films. By introducing CsI dense homogeneous perovskite films with high crystallinity, preferential orientation, and a pure black perovskite phase were prepared. In addition, the carrier lifetime of perovskite films was significantly increased because of the suppressed nonradiative recombination. Correspondingly, the power conversion efficiency (PCE) of small-area devices using CsI regulation was increased from 17.45 to 20.29%. Furthermore, the device showed excellent stability maintaining 75% of its initial PCE after 350 h of continuous irradiation. This study demonstrates that CsI-added is a reliable way to prepare PSCs for practical applications.

Keywords

Two-step deposition methodCesium halidesSpin -coatingPlanar perovskite solar cell

OpenAlex citation history

Citations by year

11 assigned citations
  1. 12023
  2. 32024
  3. 42025
  4. 32026
Source: OpenAlex · Last updated 2026-09-14. Zero-citation years are included.
View citation counts as a table
YearCitations
20231
20243
20254
20263

OpenAlex citing works

Articles citing this work

11 citing articles with DOI, from 11 records indexed by OpenAlex.

  1. Synergistic preheating and moderate temperature liquid medium annealing for high performance perovskite solar cells ↗

    Solar Energy · vol. 309, pp. 114430, 2026

    DOI: 10.1016/j.solener.2026.114430

  2. Enhancing the Optoelectronic Properties of Quasi Two‐Dimensional Perovskite by Cesium Iodide Additive ↗

    ChemistrySelect · vol. 11, no. 1, 2026

    DOI: 10.1002/slct.202503737

  3. Optimized surface engineering of zinc oxide thin films for enhanced performance of MAPbI3 perovskite layers ↗

    Journal of Materials Science Materials in Electronics · vol. 37, no. 2, 2026

    DOI: 10.1007/s10854-025-16379-2

  4. Extraction of Cesium from Lithium-Containing Freezing–Crystallization Liquor and Preparation of High-Purity Cesium Salts ↗

    JOM · vol. 78, no. 5, pp. 4093-4103, 2025

    DOI: 10.1007/s11837-025-07748-7

  5. Process Parameter Specification and Control in Solution Processing of Hybrid Perovskite Photovoltaics: From Domain‐Specific Jargon to Evidence‐Based, Unambiguous Description of Experimental Workflows ↗

    Advanced Energy Materials · vol. 15, no. 47, 2025

    DOI: 10.1002/aenm.202503187

  6. Compatibility analysis of novel inorganic cesium perovskites with emerging charge transport layers through design optimization ↗

    Energy Nexus · vol. 17, pp. 100400, 2025

    DOI: 10.1016/j.nexus.2025.100400

  7. Theoretical Investigation of the Role of Halide Alloys in the Optoelectronic and Stability Properties of Perovsites: The Example of Cs0.25MA0.25 FA0.50Pb(X ′ X X 1 – X )3 ↗

    SSRN Electronic Journal · 2025

    DOI: 10.2139/ssrn.5070883

  8. Innovations in perovskite solar cells: a journey through 2D, 3D, and 2D/3D heterojunctions ↗

    Reviews in Inorganic Chemistry · vol. 45, no. 4, pp. 687-717, 2024

    DOI: 10.1515/revic-2024-0029

  9. Unveiling the role of Cs ion in perovskite phase formation during solid–vapor reactions ↗

    Chemical Engineering Journal · vol. 499, pp. 156259, 2024

    DOI: 10.1016/j.cej.2024.156259

  10. Recent Progress of Two-step Spin-coated Formamidinium Lead-based Perovskite Solar Cells ↗

    化学学报 · vol. 82, no. 9, pp. 987, 2024

    DOI: 10.6023/a24040134

  11. New Molecular Design, Step‐Saving Synthesis, and Applications of Indolocarbazole Core‐Based Oligo(hetero)arenes ↗

    Chemistry - An Asian Journal · vol. 18, no. 20, pp. e202300681, 2023

    DOI: 10.1002/asia.202300681

← Return to publications